(2,3-Di-2-pyridylpyrazine-κ2 N 2,N 3)diiodidopalladium(II)
نویسنده
چکیده
The Pd(II) ion in the title complex, [PdI(2)(C(14)H(10)N(4))], is four-coordinated in a slightly distorted square-planar environment by the two pyridine N atoms of the chelating 2,3-di-2-pyridyl-pyrazine (dpp) ligand and two iodide anions. In the crystal, the pyridine rings are considerably inclined to the least-squares plane of the PdI(2)N(2) unit [maximum deviation = 0.090 (2) Å], making dihedral angles of 65.0 (2) and 66.6 (2)°. The pyrazine ring is perpendicular to the unit plane, with a dihedral angle of 89.9 (2)°. The complex mol-ecules are connected by C-H⋯I hydrogen bonds, forming a helical chain along the b axis.
منابع مشابه
(2,3-Di-2-pyridylpyrazine-κ2 N 2,N 3)diiodidoplatinum(II)
The Pt(II) ion in the title complex, [PtI(2)(C(14)H(10)N(4))], exists in a distorted square-planar environment defined by the two pyridine N atoms of the chelating 2,3-di-2-pyridyl-pyrazine ligand and two iodide anions. The pyridine rings are inclined to the least-squares plane of the PtI(2)N(2) unit [maximum deviation = 0.070 (3) Å] at 66.1 (2) and 65.9 (2)°; the pyrazine ring is perpendicular...
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The Pd(II) ion in the title complex, [Pd(NCS)(2)(C(14)H(10)N(4))], is four-coordinated in a distorted square-planar environment by the two pyridine N atoms of the chelating 2,3-di-2-pyridyl-pyrazine (dpp) ligand and two S atoms from two thio-cyanate anions. The pyridine rings are considerably inclined to the least-squares plane of the PdS(2)N(2) unit [maximum deviation = 0.027 (1) Å], making di...
متن کاملDibromido(2,3-di-2-pyridylpyrazine-κ2 N 2,N 3)platinum(II)
The Pt(II) ion in the title complex, [PtBr(2)(C(14)H(10)N(4))], has a slightly distorted square-planar environment defined by the two pyridyl N atoms of the chelating 2,3-di-2-pyridyl-pyrazine ligand and two bromide anions. In the crystal, the pyridyl rings are considerably inclined to the least-squares plane of the PtBr(2)N(2) unit [maximum deviation = 0.064 (2) Å] with dihedral angles of 65.2...
متن کاملDibromido(2,3-di-2-pyridylpyrazine-κ2 N 1,N 2)platinum(II)
The Pt(II) ion in the title complex, [PtBr(2)(C(14)H(10)N(4))], is four-coordinated in a distorted square-planar environment by two N atoms of a chelating 2,3-di-2-pyridyl-pyrazine ligand and two bromide anions. In the crystal, the pyridyl ring coordinated to the Pt atom is inclined slightly to its carrier pyrazine ring [dihedral angle = 14.7 (2)°], whereas the uncoordinated pyridyl ring is inc...
متن کاملDibromido(2,3-di-2-pyridylpyrazine-κ2 N 2,N 3)palladium(II)
The Pd(II) ion in the title complex, [PdBr(2)(C(14)H(10)N(4))], is four-coordinated in a slightly distorted square-planar environment by the two pyridine N atoms of the chelating 2,3-di-2-pyridyl-pyrazine (dpp) ligand and two bromide anions. The pyridine rings are considerably inclined to the least-squares plane of the PdBr(2)N(2) unit [maximum deviation = 0.080 (2) Å], making dihedral angles o...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011